I would say no. Sure, many people might know 2 or 3 off Only Revolutions and Opposites, but I’m not sure the wider interest would be there for them. Then again, Kings of Leon did it. Many people probably only knew Sex on Fire and Use Somebody, and as a band they’re boring as owt. At least Biffy would put on a cracking show.
Edit: I’ve never been to Boardmasters so I’m basing the above off the fact that I think the target they go for is what, 16 year school old leavers? Correct me if I’m wrong.